1361955-27-2

Upstream product

• 90719-32-7 (S)-4-Benzyl-2-oxazolidinone 
• 104324-16-5 (4S)-(+)-3-(chloroacetyl)-4-(phenylmethyl)-2-oxazolidinone 
• 1361955-15-8 C₁₃H₁₃NO₃S₂ 
• 513-81-5 2,3-dimethyl-buta-1,3-diene 

Relevant academic research and scientific papers

Recent developments in asymmetric hetero-diels-alder reactions of dithioesters

Recent studies dealing with asymmetric thia-Diels-Alder reactions of dithioesters as heterodienophiles are described. A diastereoselective version involving new chiral dithioesters and the first example of a catalytic enantioselective version are described. The absolute stereochemistry of the cycloadducts was assigned based on an X-ray structure and chemical correlation. In order to rationalize the sense of the chiral induction observed experimentally, stereochemical models for Cu(II)/BOX/dithioester complexes are proposed.

Asymmetric diastereoselective thia-hetero-Diels-Alder reactions of dithioesters

Asymmetric thia-Diels-Alder reactions involving new dithioesters bearing a chiral auxiliary are described, with diastereoselectivities up to 78%. Double-stereodifferentiating experiments employing chiral substrates in the presence of a chiral Lewis acid c