136201-71-3

Basic information

• Product Name: 1,2-Pentanedione, 3-methyl-1-phenyl-
• CAS NO: 136201-71-3
• Molecular Formula: C12H14O2
• Molecular Weight: 190.242
• Mol File: 136201-71-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1,2-Pentanedione, 3-methyl-1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2-Pentanedione, 3-methyl-1-phenyl-(136201-71-3)
• EPA Substance Registry System: 1,2-Pentanedione, 3-methyl-1-phenyl-(136201-71-3)

Safety Data

• Hazardous Substances Data: 136201-71-3(Hazardous Substances Data)

Upstream product

• 598-30-1 sec.-butyllithium 
• 591-51-5 phenyllithium 
• 93-58-3 benzoic acid methyl ester 
• 201230-82-2 carbon monoxide 
• 920-36-5 (2-methylpropyl)lithium 

Relevant articles and documents

One-Pot Synthesis of Unsymmetrical Ketones by the Reaction of Decacarbonyldimanganese with Two Kinds of Alkyllithiums

Decacarbonyldimanganese (Mn2(CO)10) is utilized as a phosgene equivalent for the one-pot preparation of unsymmetrical ketones. By a successive treatment of Mn2(CO)10 with two kinds of alkyllithiums, unsymmetrical ketones are obtained in high selectivity. Unsymmetrical α-diketones are generated when the above reaction is carried out in the presence of trimethyl phosphite and is quenched with N-bromosuccinimide.