1362387-29-8

Basic information

• Product Name: allyl 1-(4-methoxybenzyl)-2-oxocyclopentanecarboxylate
• Synonyms: allyl 1-(4-methoxybenzyl)-2-oxocyclopentanecarboxylate
• CAS NO: 1362387-29-8
• Molecular Weight: 288.343
• Mol File: 1362387-29-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: allyl 1-(4-methoxybenzyl)-2-oxocyclopentanecarboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: allyl 1-(4-methoxybenzyl)-2-oxocyclopentanecarboxylate(1362387-29-8)
• EPA Substance Registry System: allyl 1-(4-methoxybenzyl)-2-oxocyclopentanecarboxylate(1362387-29-8)

Safety Data

• Hazardous Substances Data: 1362387-29-8(Hazardous Substances Data)

Upstream product

• 75265-67-7 allyl 2-oxocyclopentane-1-carboxylate 
• 824-94-2 p-methoxybenzyl chloride 

Downstream Products

• 1362388-11-1 (S)-2-allyl-2-(4-methoxybenzyl)cyclopentanone 

Relevant articles and documents

Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Cyclopentanones

The first general method for the enantioselective construction of all-carbon quaternary centers on cyclopentanones by enantioselective palladium-catalyzed decarboxylative allylic alkylation is described. Employing the electronically modified (S)-(p-CF3)3-t-BuPHOX ligand, α-quaternary cyclopentanones were isolated in yields up to >99% with ee's up to 94%. Additionally, in order to facilitate large-scale application of this method, a low catalyst loading protocol was employed, using as little as 0.15 mol % Pd, furnishing the product without any loss in ee.