1362388-13-3

Basic information

• Product Name: (S)-2-allyl-2-(4-methylbenzyl)cyclopentanone
• Synonyms: (S)-2-allyl-2-(4-methylbenzyl)cyclopentanone
• CAS NO: 1362388-13-3
• Molecular Weight: 228.334
• Mol File: 1362388-13-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (S)-2-allyl-2-(4-methylbenzyl)cyclopentanone(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-2-allyl-2-(4-methylbenzyl)cyclopentanone(1362388-13-3)
• EPA Substance Registry System: (S)-2-allyl-2-(4-methylbenzyl)cyclopentanone(1362388-13-3)

Safety Data

• Hazardous Substances Data: 1362388-13-3(Hazardous Substances Data)

Upstream product

• 54158-56-4 2-(p-methylbenzyl)cyclopentanone 
• 15022-08-9 diallylcarbonate 
• 75265-67-7 allyl 2-oxocyclopentane-1-carboxylate 
• 104-81-4 4-Methylbenzyl bromide 
• 1362387-31-2 allyl 1-(4-methylbenzyl)-2-oxocyclopentanecarboxylate 

Relevant articles and documents

Palladium-Catalyzed Enantioselective Decarboxylative Allylic Alkylation of Cyclopentanones

The first general method for the enantioselective construction of all-carbon quaternary centers on cyclopentanones by enantioselective palladium-catalyzed decarboxylative allylic alkylation is described. Employing the electronically modified (S)-(p-CF3)3-t-BuPHOX ligand, α-quaternary cyclopentanones were isolated in yields up to >99% with ee's up to 94%. Additionally, in order to facilitate large-scale application of this method, a low catalyst loading protocol was employed, using as little as 0.15 mol % Pd, furnishing the product without any loss in ee.