136269-32-4Relevant academic research and scientific papers
Phosphorus(V)-catalyzed deoxydichlorination reactions of aldehydes
An, Jie,Tang, Xiaoping,Moore, Joshua,Lewis, William,Denton, Ross M.
, p. 8769 - 8776 (2013/09/23)
A phosphine oxide-catalyzed conversion of aldehydes into 1,1-dichlorides is reported. The reaction proceeds via a phosphorus(V)-catalysis manifold in which phosphine oxide turnover is achieved using oxalyl chloride as a consumable reagent. The new method is applicable to a range of aldehydes and, in combination with palladium-catalyzed reductive dimerization, gives rise to a new catalytic approach to the synthesis of stilbenes and a short formal synthesis of resveratrol.
Process for opening cyclopropane rings
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, (2008/06/13)
Process for ring opening compounds of the formula STR1 in which R1 is heteroaryl or aryl, R2 is a leaving group, R3, R4, R5 and R6 are independently selected from hydrogen, alkyl, aralkyl,
