136269-37-9Relevant academic research and scientific papers
TIME-RESOLVED FLASH SPECTROSCOPIC INVESTIGATIONS OF THE REACTIONS OF SINGLET ARYLHALOCARBENES
Gould, I. R.,Turro, N. J.,Butcher, J.,Doubleday, C.,Hacker, N. P.,et al.
, p. 1587 - 1600 (1985)
The results of time-resolved laser flash spectrmetric studies of singlet arylhalocarbenes are reviewed.In particular, the absolute rate constants for reactions of phenylchlorocarbene and related carbenes with alkenes are summarized and systematized.The experiments described provide the basis for a detailed examination of carbenic reactivity-selectivity principles.The results of studies on the influence of temperature on the absolute rate constants for carbene reactions are consistent with the existence of transient carbene/alkene intermediates.
A Tandem Silica-induced Ring-opening and Cyclization of 1-Aryl-1-chlorocyclopropanes leading to Indenes
Baird, Mark S.,Dacre, Richard,Tomkinson, Jeremy
, p. 535 - 538 (2007/10/02)
Reaction of a number of methoxy-substituted 1-aryl-1-chloro-2-methylcyclopropanes with silica and carbon tetrachloride at 20 deg C leads to indenes, in a process which may involve ring-opening to a diene with loss of HCl, followed by acid-induced cyclisat
Process for opening cyclopropane rings
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, (2008/06/13)
Process for ring opening compounds of the formula STR1 in which R1 is heteroaryl or aryl, R2 is a leaving group, R3, R4, R5 and R6 are independently selected from hydrogen, alkyl, aralkyl,
HAMMETT ANALYSIS OF ABSOLUTE CARBENE ADDITION RATE CONSTANTS
Moss, R.A.,Perez, L.A.,Turro, N.J.,Gould, I.R.,Hacker, N.P.
, p. 685 - 688 (2007/10/02)
Absolute rate constants were determined for the additions of 5 p-X-substituted ArCCl (X=CF3, Cl, H, CH3, CH3O) to tetramethylethylene, trimethylethylene, trans-pentene, and 1-hexene; good Hammett correlations were obtained with ρ= +1.4 - 1.6.
