136290-36-3Relevant academic research and scientific papers
A synthesis of multisubstituted vinylsilanes via ynolates: Stereoselective formation of β-silyl-β-lactones followed by decarboxylation
Shindo, Mitsuru,Matsumoto, Kenji,Shishido, Kozo
, p. 2477 - 2479 (2007/10/03)
(Z)-Selective synthesis of multisubstituted vinylsilanes was achieved by stereoselective protonation or alkylation of β-silyl-β-lactone enolates, prepared by cycloadditions of acylsilanes with ynolates, followed by decarboxylation. The Royal Society of Ch
Lewis acid catalyzed highly regio- and stereocontrolled trans- hydrosilylation of alkynes and allenes
Sudo,Asao,Gevorgyan,Yamamoto
, p. 2494 - 2499 (2007/10/03)
Lewis acids such as AlCl3 or EtAlCl2 dramatically catalyzed the hydrosilylation of alkynes 1 with trialkylsilanes to produce the corresponding cis-vinylsilanes 2 in a regio- and trans-stereoselective manner. For example, the hydrosil
Group 6 anionic ·-hydride complexes [HM2(CO)10]- (M = Cr, Mo, W): New catalysts for hydrogenation and hydrosilylation
Fuchikami, Takamasa,Ubukata, Yumiko,Tanaka, Yasutaka
, p. 1199 - 1202 (2007/10/02)
Group 6 anionic ·-hydride complexes catalyze hydrogenation of conjugated olefins, aldehydes, ketoesters, and alkynes, and hydrosilylation of aldehydes and conjugated olefins with high regio- and stereoselectivity. Ketones are converted into silyl ethers and silyl enol ethers with monohydrosilanes and dihydrosilanes, respectively.
