136305-60-7

Upstream product

• 69739-34-0 t-butyldimethylsiyl triflate 
• 136305-59-4 methyl 4,5,7-tri-O-benzyl-α-D-gluco-hept-2-ulopyranosonate 
• 127994-68-7 methyl onate 
• 110390-66-4 methyl (4R,5S,6R)-4,5-bis(benzyloxy)-6-(benzyloxymethyl)-5,6-dihydro-4H-pyran-2-carboxylate 

Downstream Products

• 136305-49-2 (3R,4S,5R,6R)-4,5-Bis-benzyloxy-6-benzyloxymethyl-3-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-tetrahydro-pyran-2-carboxylic acid 
• 136305-51-6 methyl (methyl 4,5,7-tri-O-benzyl-3-O-t-butyldimethylsilyl-α/β-D-gluco-hept-2-ulopyranosid)onate 
• 136305-66-3 methyl 3,4,6-tri-O-benzyl-2-O-t-butyldimethylsilyl-β-D-glucopyranoside 
• 40246-30-8 methyl 3,4,6-tri-O-benzyl-β-D-glucopyranoside 
• 137500-98-2 methyl 4,5,7-tri-O-benzyl-3-O-t-butyldimethylsilyl-2-deoxy-2-fluoro-α/β-D-gluco-hept-2-ulopyranosonate 
• 136305-50-5 methyl 4,5,7-tri-O-benzyl-3-O-t-butyldimethylsilyl-2-chloro-2-deoxy-α/β-D-gluco-hept-2-ulopyranosonate 

Relevant academic research and scientific papers

Diastereoselective radical reactions : β-face selective quenching of the 1,2-O-isopropylidene-3,4,6-tri-O-benzyl-D-glucopyranos-1-yl radical

Pyrolysis of 3,4,6-tri-Obenzyl-1-carbomethoxy-1,2-dideoxy-1-phenylsulfonyl-D-glucopyranose provides the corresponding 1-carbomethoxyglucal which reacts with osmium tetroxide to form a gluco-diol. This diol is converted to an acetonide which is saponified

Diastereoselective Free-Radical Reactions. Part 3. The Methyl Glucopyranos-1-yl and 1,2-O-Isopropylideneglucopyranos-1-yl Radicals: Conformational Effects on Diastereoselectivity

The 3,4,6-tri-O-benzyl-2-O-t-butyldimethylsilyl-1-O-methyl-D-glucopyranos-1-yl and the 3,4,6-tri-O-benzyl-1,2-O-isopropylidene-D-glucopyranos-1-yl radicals are quenched with high selectivity (>25:1) from the α- and β-face, respectively, by t-dodecanethiol