1363322-01-3

Basic information

• Product Name: [(3,5-di-tert-butylsalicylaldehydato)(N-(2-phenylethyl)-3,5-di-tert-butyl-salicylaldiminato)]copper(II)
• CAS NO: 1363322-01-3
• Molecular Weight: 633.374
• Mol File: 1363322-01-3.mol

Chemical Properties

• CAS DataBase Reference: [(3,5-di-tert-butylsalicylaldehydato)(N-(2-phenylethyl)-3,5-di-tert-butyl-salicylaldiminato)]copper(II)(CAS DataBase Reference)
• NIST Chemistry Reference: [(3,5-di-tert-butylsalicylaldehydato)(N-(2-phenylethyl)-3,5-di-tert-butyl-salicylaldiminato)]copper(II)(1363322-01-3)
• EPA Substance Registry System: [(3,5-di-tert-butylsalicylaldehydato)(N-(2-phenylethyl)-3,5-di-tert-butyl-salicylaldiminato)]copper(II)(1363322-01-3)

Safety Data

• Hazardous Substances Data: 1363322-01-3(Hazardous Substances Data)

Upstream product

• 1018900-74-7 bis-(3,5-di-tert-butylsalicylaldehydato) copper(II) 
• 64-04-0 phenethylamine 
• 1203602-32-7 bis[(N-(2-phenylethyl)-3,5-di-tert-butyl-salicylaldiminato)]copper(II) 
• 37942-07-7 3,5-di-tert-butyl-2-hydroxybenzaldehyde 
• 1203602-28-1 N-(2-phenylethyl)-3,5-di-tert-butylsalicylaldimine 
• 142-71-2 copper diacetate 

Relevant articles and documents

A facile synthesis of mixed ligand Cu(II) complexes with salicylaldehyde and salicylaldimine ligands and their X-ray structural characterization

High yield synthetic routes to the preparation of new mixed ligand Cu(II) complexes (1-7) derived from a sterically hindered salicylaldimine and the corresponding salicylaldehyde have been developed. The complexes could be obtained either forming a salicylaldimine preligand or two optional Cu(II) complex precursors. One-pot synthesis could also be used. The complexes have been fully characterized by means of elemental analysis, UV-Vis and IR spectroscopy. Crystal structures obtained for four [(3,5-di-tert- butylsalicylaldehydato)(N-R-3,5-di-tert-butylsalicylaldiminato)]Cu(II) (where R = phenyl (1), isopropyl (3), benzyl (5) and 2-phenylethyl (6)) complexes show that three of them are cis-isomers and one is a trans-isomer with respect to the phenolic O-atoms. Complexes 1, 5 and 6 form preferably loose dimers while 3 favors to exist in a loose polymeric structure in a crystal. In all these polynuclear forms the geometry around the Cu(II) ions is a distorted octahedron.