136339-23-6

Upstream product

• 67957-91-9 2-methyl-1-cyclohexenyl phenyl sulfide 
• 931-59-9 benzenesulfenyl chloride 
• 136339-39-4 (7-Chloro-hepta-1,2-diene-3-sulfinyl)-benzene 
• 1002-50-2 7-chloro-2-heptyn-1-ol 
• 583-60-8 2-Methylcyclohexanone 
• 108-98-5 thiophenol 
• 136339-12-3 (7-Iodo-hepta-1,2-diene-3-sulfinyl)-benzene 

Relevant academic research and scientific papers

Synthesis of α-methylene-β-hydroperoxy sulfoxides by regioselective photooxygenation (Schenck Reaction) of racemic vinyl sulfoxides

The β-hydroperoxy vinyl sulfoxides 3 were synthesized in good to excellent yields by regioselective photooxygenation of racemic vinyl sulfoxides 2. Moderate diastereoselectivities were observed in the ene reaction of singlet oxygen (Schenck Reaction) with

Radical cyclizations of functionalized allenes

Substitution of P(O)Ph2, SOPh, and SO2Ph on an allene facilitates intramolecular radical addition to the central allene carbon to provide good yields of five-, six-, and seven-membered carbocycles.