1363553-52-9

Upstream product

• 26726-81-8 1,2-bis(bromomethyl)-4,5-dimethoxybenzene 
• 1134-52-7 1,2-Dimethoxy-4,5-bis(chloromethyl)benzene 
• 91-16-7 1,2-dimethoxybenzene 
• 1363553-50-7 methyl 2-((2-(chloromethyl)-4,5-dimethoxybenzyl)((2,2,2-trichloroethoxy)carbonyl)amino)pent-4-enoate 
• 1363553-46-1 Br^(1-)*C₁₆H₂₂NO₄⁽¹⁺⁾ 

Downstream Products

• 50299-15-5 allylglycine methyl ester 

Relevant academic research and scientific papers

1,2-Dimethoxy-4,5-dimethylene: A new protecting group for acyclic amino acid derivatives prepared by Stevens rearrangement

A new protecting group, 1,2-dimethoxy-4,5-dimethylene, for acyclic amino acid derivatives could be introduced by N,N-dialkylation with 1,2-bis(bromomethyl)-4,5-dimethoxybenzene (1) and removed via amine de-alkylation with acyl chlorides. The method can be used with base-induced [2,3] and [1,2] Stevens rearrangement products.