136369-48-7

Upstream product

• 136369-53-4 [(S)-2-(2-Bromo-1-ethoxy-ethoxy)-but-3-ynyloxymethyl]-benzene 
• 136369-54-5 (S)-5-Benzyloxy-4-(2-bromo-1-ethoxy-ethoxy)-pent-2-ynoic acid methyl ester 
• 136369-47-6 (Z)-5-Benzyloxy-4-(2-bromo-1-ethoxy-ethoxy)-pent-2-enoic acid methyl ester 

Downstream Products

• 136369-46-5 (1R,5R,6S)-6-Benzyloxymethyl-2,7-dioxa-bicyclo[3.2.1]octan-3-one 
• 136369-58-9 ((2S,3R)-2-Benzyloxymethyl-5-ethoxy-tetrahydro-furan-3-yl)-thioacetic acid O-methyl ester 
• 136369-50-1 [(2S,3R,5S)-5-(4-Amino-2-oxo-2H-pyrimidin-1-yl)-2-benzyloxymethyl-tetrahydro-furan-3-yl]-thioacetic acid O-methyl ester 
• 136369-49-8 [(2S,3R,5R)-5-(4-Amino-2-oxo-2H-pyrimidin-1-yl)-2-benzyloxymethyl-tetrahydro-furan-3-yl]-thioacetic acid O-methyl ester 
• 136369-51-2 Acetic acid (4R,5S)-5-benzyloxymethyl-4-methoxythiocarbonylmethyl-tetrahydro-furan-2-yl ester 

Relevant academic research and scientific papers

Asymmetric synthesis of 3′-carbomethoxymethyl 3′-deoxythymidine via radical cyclization

An efficient asymmetric synthesis of 3′-C-carbomethoxymethyl- 3′-deoxythymidine 2, using a highly stereocontrolled radical cyclization from bromoacetai 7 to furanose 8, followed by a dimethylboron bromide mediated nucleoside formation, is described. A 96: