136370-27-9

Basic information

• Product Name: Phenyl 1,2,2-trifluoroethyl sulfide
• Synonyms: Phenyl 1,2,2-trifluoroethyl sulfide
• CAS NO: 136370-27-9
• Molecular Weight: 192.205
• Mol File: 136370-27-9.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Phenyl 1,2,2-trifluoroethyl sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: Phenyl 1,2,2-trifluoroethyl sulfide(136370-27-9)
• EPA Substance Registry System: Phenyl 1,2,2-trifluoroethyl sulfide(136370-27-9)

Safety Data

• Hazardous Substances Data: 136370-27-9(Hazardous Substances Data)

Upstream product

• 134024-36-5 2,2-difluoroethyl phenyl sulfide 

Relevant articles and documents

Electrolytic Partial Fluorination of Organic Compounds. 12. Selective Anodic Monofluorination of Fluoroalkyl and Alkyl Sulfides

Highly regioselective anodic monofluorination of various aryl and alkyl fluoroalkyl sulfides was successfully carried out, and fluorine was exclusively (aryl sulfides) or preferentially (alkyl sulfides) introduced at the position α to the fluoroalkyl group.Even simple alkyl phenyl sulfides devoid of an electron-withdrawing group could be anodically monofluorinated in satisfactory yields for the first time when etheral solvents were used as an electrolytic solution.A unique Pummerer-type mechanism via fluorosulfonium ions was proposed for this anodic fluorination by comparison with anodic α-methoxylation previously studied.