1363721-93-0

Basic information

• Product Name: (2S,3R)-3-fluoro-3-{2-[(S)-p-tolylsulfinyl]phenyl}-2-(4-tolyl)-prop-1-yl phenyl sulfone
• Synonyms: (2S,3R)-3-fluoro-3-{2-[(S)-p-tolylsulfinyl]phenyl}-2-(4-tolyl)-prop-1-yl phenyl sulfone
• CAS NO: 1363721-93-0
• Molecular Weight: 506.662
• Mol File: 1363721-93-0.mol

Chemical Properties

• CAS DataBase Reference: (2S,3R)-3-fluoro-3-{2-[(S)-p-tolylsulfinyl]phenyl}-2-(4-tolyl)-prop-1-yl phenyl sulfone(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,3R)-3-fluoro-3-{2-[(S)-p-tolylsulfinyl]phenyl}-2-(4-tolyl)-prop-1-yl phenyl sulfone(1363721-93-0)
• EPA Substance Registry System: (2S,3R)-3-fluoro-3-{2-[(S)-p-tolylsulfinyl]phenyl}-2-(4-tolyl)-prop-1-yl phenyl sulfone(1363721-93-0)

Safety Data

• Hazardous Substances Data: 1363721-93-0(Hazardous Substances Data)

Upstream product

• 101093-66-7 C₁₅H₁₄O₂S 
• 1311404-00-8 1-(fluoromethyl)-2-[(S)-p-tolylsulfinyl]benzene 

Relevant articles and documents

Stereocontrolled fluorobenzylation of vinyl sulfones and α,β-unsaturated esters mediated by a remote sulfinyl group. Synthesis of functionalized enantiomerically pure benzylic fluorides

A sulfinyl group in an ortho position confers enough chemical and configurational stability to monofluorobenzylcarbanions to evolve in a completely stereoselective way in their reactions with β-substituted vinyl sulfones and α,β-unsaturated esters. Reactions afford easily separable mixtures of two epimers differing in the configuration of the center derived from the Michael acceptor (up to 98% de). They can be easily converted into enantiomerically pure γ-fluorinated γ-phenylsulfones and γ-phenylesters bearing two chiral centers.