1363728-53-3Relevant academic research and scientific papers
Rhodium-catalyzed carbonylation of 3-acyloxy-1,4-enynes for the synthesis of cyclopentenones
Li, Xiaoxun,Huang, Suyu,Schienebeck, Casi M.,Shu, Dongxu,Tang, Weiping
supporting information; experimental part, p. 1584 - 1587 (2012/05/07)
Functionalized cyclopentenones were synthesized by a Rh-catalyzed carbonylation of 3-acyloxy-1,4-enynes, derived from alkynes and α,β-unsaturated aldehydes. The reaction involved a Saucy-Marbet 1,3-acyloxy migration of propargyl esters and a [4 + 1] cycloaddition of the resulting acyloxy substituted vinylallene with CO.
