136374-60-2Relevant academic research and scientific papers
Synthesis and X-ray crystal structure of trans-dichloro(1-cyano-2,2-dimethylpropane)(1-imino-1-hydroxy-2,2- dimethylpropane)platinum(II)
Cini, Renzo,Cavaglioni, Alessandro,Intini, Francesco P.,Fanizzi, Francesco P.,Pacifico, Concetta,Natile, Giovanni
, p. 1863 - 1868 (2008/10/09)
Nitrile complexes of platinum easily hydrolyze to amidate, amide, and mixed amide-nitrile complexes. The amide ligands generally adopt the enol tautomeric form and coordinate to platinum through nitrogen. A mixed amide-nitrile complex, trans-[PtCl2{HN=C(OH)C(CH3) 3}{N≡CC(CH3)3}] (trans-3), has shown to be the complex previously formulated as a platinum(IV) dichlorobisamidate derivative having the two amidate ligands in different tautomeric forms. The structure of trans-3 has been solved by single-crystal diffraction. The complex crystallizes in the Pbcn space group. The crystal structure has strong similarities with that previously reported by some of us for trans-[PtCl2{HN=C(OH)C(CH3)3}2] [R. Cini, F.P. Fanizzi, F.P. Intini, C. Pacifico, G. Natile, Inorg. Chim. Acta 264 (1997) 279]. Triplets of complex molecules are stabilized by intra-molecular hydrogen bonds involving N, Cl and O atoms. Elsevier Science Ltd.
Platinum amides from platinum nitriles: X-ray crystal structures of the unbridged dinuclear compounds bis[bis(1-imino-1-hydroxy-2,2-dimethylpropane)dichloro-platinum(II)] and bis[bis(1-imino-1-hydroxy-2,2-dimethyl-propane)(1-amino-1-oxo-2,2- dimethylpropa
Cini, Renzo,Fanizzi, Francesco P.,Intini, Francesco P.,Maresca, Luciana,Natile, Giovanni
, p. 5123 - 5131 (2007/10/02)
Mono- and bisnitrile platinum complexes, [PtCl3(NCR)]- and cis- and trans-[PtCl2(NCR)2] (R = But, Me and Ph), hydrolyze to amidate amide and mixed amide-nitrile complexes. The amide ligands generally
