136382-99-5Relevant academic research and scientific papers
Controllable Activation of Pd-G3 Palladacycle Precatalyst in the Presence of Thiosugars: Rapid Access to 1-Aminobiphenyl Thioglycoside Atropoisomers at Room Temperature
AL-Shuaeeb, Riyadh Ahmed Atto,Dejean, Camille,Alami, Mouad,Messaoudi, Samir
, p. 3114 - 3118 (2017)
A controllable method for the functionalization of XantPhos Pd-G3 precatalyst with thiosugars and thiols has been established. Under mild and operationally simple reaction conditions through just mixing of precatalyst and thiosugars (α- or β-mono-, di- and poly-thiosugar derivatives) in water at 25 °C for 20 min, a series of 1-aminobiphenyl thioglycosides that are difficult to synthesize by classical methods has been synthesized in very high yields.
Syntheses and Thermal Behaviour of 9-Substituted 9-Thia-10-azaphenanthrenes
Shimizu, Hiroshi,Ikedo, Koji,Hamada, Koji,Ozawa, Michinori,Matsumoto, Harutoshi,et al.
, p. 1733 - 1747 (2007/10/02)
Synthetic approaches to a variety of 9-thia-10-azaphenanthrenes having various kinds of substituent at the 9-position were investigated.Their thermal stabilities were found to be depend strongly upon the nature of the substituents on the sulphur atom.Seve
