136464-77-2

Upstream product

• 34837-55-3 Phenylselenyl bromide 
• 136464-68-1 Methyl (1R*,2R*,10R*)-1,10-dimethyl-5-oxobicyclo<4.4.0>dec-6-ene-2-carboxylate 
• 136464-70-5 Methyl 5-(1,3-dioxolan-2-yl)-2-<(1R*,2R*)-5,5-ethylenedioxy-1,2-dimethylcyclohexyl>valerate 
• 122689-33-2 Methyl (1S*,2R*)-1,2-dimethyl-5-oxocyclohexylacetate Ethylene Acetal 
• 136464-72-7 Methyl (1R*,2R*,5R*,6S*,10R*)-1,10-dimethyl-7-oxo-5,6-epoxybicyclo<4.4.0>decane-2-carboxylate 
• 136464-73-8 Methyl (1R*,2R*,5R*,10R*)-5-hydroxy-1,10-dimethylbicyclo<4.4.0>dec-6-ene-2-carboxylate 
• 136464-69-2 Methyl (1R*,2R*,10R*)-1,10-dimethyl-7-oxobicyclo<4.4.0>dec-5-ene-2-carboxylate 

Relevant academic research and scientific papers

Total Synthesis of Kanshone A, a Sesquiterpene Isolated from Nardostachys chinensis (Valerianaceae)

Kanshone A, isolated from Nardostachys chinensis (Valerianaceae), has been synthesized in 9 steps by stereoselective alkylation of the derivative methyl (5,5-ethylenedioxy-1,2-dimethylcyclohexyl)acetate and an intramolecular aldol cyclization followed by methylation and introduction of a double bond