1364975-40-5Relevant academic research and scientific papers
ENANTIOPURE BASE-METAL CATALYSTS FOR ASYMMETRIC CATALYSIS AND BIS(IMINO)PYRIDINE IRON ALKYL COMPLEXES FOR CATALYSIS
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Paragraph 0145; 0146; 0147, (2013/04/10)
Disclosed herein are iron, nickel, or cobalt compounds having tridentate ligands, which can have at least one chiral moiety in the molecular structure thereof and the use of these compounds for the hydrogenation and transformation of olefins (preferably prochiral) and alkynes.
Enantiopure C1-symmetric bis(imino)pyridine cobalt complexes for asymmetric alkene hydrogenation
Monfette, Sebastien,Turner, Zoe R.,Semproni, Scott P.,Chirik, Paul J.
, p. 4561 - 4564 (2012/04/23)
Enantiopure C1-symmetric bis(imino)pyridine cobalt chloride, methyl, hydride, and cyclometalated complexes have been synthesized and characterized. These complexes are active as catalysts for the enantioselective hydrogenation of geminal-disubstituted olefins.
