1365148-30-6

Basic information

• Product Name: (CH₃O)3Si(CH₂)3N((CH₂)3NCHC₆H₃Cl(OH))2
• Synonyms: (CH₃O)3Si(CH₂)3N((CH₂)3NCHC₆H₃Cl(OH))2
• CAS NO: 1365148-30-6
• Molecular Weight: 570.588
• Mol File: 1365148-30-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (CH₃O)3Si(CH₂)3N((CH₂)3NCHC₆H₃Cl(OH))2(CAS DataBase Reference)
• NIST Chemistry Reference: (CH₃O)3Si(CH₂)3N((CH₂)3NCHC₆H₃Cl(OH))2(1365148-30-6)
• EPA Substance Registry System: (CH₃O)3Si(CH₂)3N((CH₂)3NCHC₆H₃Cl(OH))2(1365148-30-6)

Safety Data

• Hazardous Substances Data: 1365148-30-6(Hazardous Substances Data)

Upstream product

• 294628-84-5 C₂₀H₂₃Cl₂N₃O₂ 
• 14867-28-8 3-iodopropyltrimethoxysilane 

Relevant articles and documents

Single site anchored novel Cu(II) catalysts for selective liquid-gas phase O2 oxidation of n-alkanes

The pentacoordinate schiff-base trialkoxysilane Cu(II) complexes, i.e. Cu[Sal(PMeOSi)DPTA], (III-a) and Cu[Cl-Sal(PMeOSi)DPTA], (III-b) were synthesized and covalently anchored on SiO2 and Al2O 3 matrixes as supported hybrid catalysts (i.e. III-a/SiO2 as Catal.-1, III-b/SiO2 as Catal.-2, III-a/Al2O 3 as Catal.-3 and III-b/Al2O3 as Catal.-4). The characterization of supported Cu(II) complexes were performed with SEM-EDX, TGA, ICP, FT-IR and EPR analysis. Catalytic tests were conducted in the oxidation (O2) of n-alkanes under relatively mild conditions, in a batch rocking type reactor. Remarkable high catalytic TONs, from 1468 up to 2422, were observed. Catal.-2 provided the best overall yield, 25.2% with 92% selectivity for n-hexane and 20.1% with 75% selectivity for n-heptane. A 20% improvement in the yields was obtained with PCA as co-catalyst. The impact of both C- and O- centred radical traps were also assessed in order to establish a radical mechanism.