136537-06-9

Upstream product

• 136537-03-6 (2S,3S)-3-azido-4-O-tert-butyldiphenylsilyl-1,2-O-isopropylidene-1,2,4-butanetriol 
• 136537-04-7 (2S,3S)-3-amino-4-O-tert-butyldiphenylsilyl-1,2-O-isopropylidene-1,2,4-butanetriol 
• 24424-99-5 di-tert-butyl dicarbonate 
• 160427-58-7 methyl (2R)-2-[(tert-butylcarbonyl)amino]-2-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]ethanoate 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 136537-05-8 (2S,3S)-3-tert-butoxycarbonylamino-4-O-tert-butyldiphenylsilyl-1,2-O-isopropylidene-1,2,4-butanetriol 
• 851960-01-5 [(S)-1-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2-hydroxy-ethyl]-carbamic acid tert-butyl ester 

Downstream Products

• 136537-07-0 Toluene-4-sulfonic acid (2S,3S)-3-tert-butoxycarbonylamino-4-(tert-butyl-diphenyl-silanyloxy)-2-hydroxy-butyl ester 
• 136537-08-1 (2S,3S)-2-tert-butoxycarbonylamino-1-O-tert-butyldiphenylsilyl-3,4-epoxy-1-butanol 
• 136537-12-7 (Z)-(2S,3R)-2-Amino-1-(tert-butyl-diphenyl-silanyloxy)-octadec-8-en-3-ol; compound with trifluoro-acetic acid 
• 136537-12-7 (E)-(2S,3R)-2-Amino-1-(tert-butyl-diphenyl-silanyloxy)-octadec-8-en-3-ol; compound with trifluoro-acetic acid 
• 136537-10-5 (2S,3R,8Z)-2-N-tert-butoxycarbonyl-1-O-tert-butyldiphenylsilyl-8-sphingenine 
• 136537-17-2 (2S,3R,8E)-2-N-tert-butoxycarbonyl-1-O-tert-butyldiphenylsilyl-8-sphingenine 

Relevant academic research and scientific papers

Ozonolyses of enantiopure 4-alkoxy-3,6-dihydro-2H-1,2-oxazines: An expedient route to functionalized α-amino-β-hydroxy esters

Ozonolysis and subsequent in situ acylation/base treatment converted the enantiopure carbohydrate-derived 1,2-oxazines 1, 5, 8 (either syn- or anti-configured) and anti-11 into the highly functionalized α-amino- β-hydroxy esters 2, 6, 9 and 12 in moderate

Synthesis of Sphingosine Relatives, XI: Synthesis of Wheat Grain Cerebroside with Fruiting-Inducing Effect on Schizophyllum commune

(2S,3R,8Z)-1-O-(β-D-Glucopyranosyl)-N-hexadecanoyl-8-sphingenine (1) and its (8E) isomer 1(E) were synthesized by starting from D-(-)-tartaric acid.Key Words: Cerebroside / Sphingosine, dihydro / Tartaric acid