13654-48-3

Upstream product

• 110-91-8 morpholine 
• 96-22-0 pentan-3-one 

Downstream Products

• 1187-04-8 4-methyl-3,5-heptanedione 
• 13618-19-4 1-phenyl-2-methyl-1,3-pentanedione 
• 21088-37-9 4-(3-ethyl-4-methyl-2,2-diphenyl-oxetan-3-yl)-morpholine 
• 20990-21-0 2,4,5-trimethyl-3-morpholin-4-yl-cyclohex-2-enone 
• 28403-15-8 2,4-dimethyl-3-morpholin-4-yl-phenol 
• 41097-89-6 3,4-Diphenyl-hept-4-en-2-on 
• 97790-98-2 4-[5-ethyl-4-methyl-3-(4-nitro-phenyl)-4,5-dihydro-isoxazol-5-yl]-morpholine 
• 20990-19-6 2,4-dimethyl-3-morpholin-4-yl-cyclohex-2-enone 
• 41315-12-2 2.4-Dimethyl-cyclohexan-dion-(1.3) 
• 13618-27-4 1-cyclohexyl-2-methyl-pentane-1,3-dione 
• 97598-54-4 4-(4-ethyl-5-methyl-3-phenyl-4,5-dihydro-3H-[1,2,3]triazol-4-yl)-morpholine 
• 20990-23-2 2,4,6-trimethyl-3-morpholin-4-yl-cyclohex-2-enone 
• 82491-73-4 2-Ethyl-2-morpholin-4-yl-3-phenylselanyl-butyronitrile 
• 79379-54-7 6-Ethyl-5-methyl-6-morpholin-4-yl-3-phenyl-5,6-dihydro-4H-[1,2]oxazine 

Relevant academic research and scientific papers

Visible light induced photocatalytic conversion of enamines into amides

A series of enamines were photocatalytically cleaved to produce amide products under simple visible-light irradiation from a 45 W household light bulb. Mechanistically, the reactions appear to involve photosensitized formation of a singlet oxygen intermediate and a subsequent [2+2] cycloaddition event. Georg Thieme Verlag Stuttgart, New York.

Optimum Conditions for Enamine Synthesis by an Improved Titanium Tetrachloride Procedure

A modified procedure for enamine synthesis which results in shorter times and increased yield has been developed.Optimum conditions for the synthesis have been obtained from a series of eight different acyclic ketones with three different amines.The optimum conditions were determined either by response surface methodologgy or by simplex technique.In view of the results some consideration of the mechanism is briefly discussed.

The Chemistry of Aryllead(IV) Tricarboxylates. Reaction with Enamines

The treatment of 1-morhpholinocyclopentene (1a) with p-methoxyphenyllead triacetate (2a) in chloroform provides a simple high-yielding route to 2-(4-methoxyphenyl)cyclopentanone (3a).This arylation reaction of enamines has been investigated with a variety of substrates and a number of aryllead triacetates.The reaction has been found to be very sensitive to steric effects and is thus a useful synthetic method in a relatively small number of cases.Acetoxylation is a major competing reaction with those enamines of cyclic ketones which give a low to moderate yield of arylated product.