13654-48-3

Basic information

• Product Name: Morpholine, 4-(1-ethyl-1-propenyl)- (9CI)
• Synonyms: Morpholine, 4-(1-ethyl-1-propenyl)- (9CI)
• CAS NO: 13654-48-3
• Molecular Formula: C₉H₁₇NO
• Molecular Weight: 155.24
• Mol File: 13654-48-3.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 89 °C(Press: 16 Torr)
• Appearance: /
• Density: 0.937±0.06 g/cm3(Predicted)
• PKA: 6.11±0.50(Predicted)
• CAS DataBase Reference: Morpholine, 4-(1-ethyl-1-propenyl)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Morpholine, 4-(1-ethyl-1-propenyl)- (9CI)(13654-48-3)
• EPA Substance Registry System: Morpholine, 4-(1-ethyl-1-propenyl)- (9CI)(13654-48-3)

Safety Data

• Hazardous Substances Data: 13654-48-3(Hazardous Substances Data)

Upstream product

• 110-91-8 morpholine 
• 96-22-0 pentan-3-one 

Downstream Products

• 21088-37-9 4-(3-ethyl-4-methyl-2,2-diphenyl-oxetan-3-yl)-morpholine 
• 20990-21-0 2,4,5-trimethyl-3-morpholin-4-yl-cyclohex-2-enone 
• 28403-15-8 2,4-dimethyl-3-morpholin-4-yl-phenol 
• 41097-89-6 3,4-Diphenyl-hept-4-en-2-on 
• 97790-98-2 4-[5-ethyl-4-methyl-3-(4-nitro-phenyl)-4,5-dihydro-isoxazol-5-yl]-morpholine 
• 20990-19-6 2,4-dimethyl-3-morpholin-4-yl-cyclohex-2-enone 
• 41315-12-2 2.4-Dimethyl-cyclohexan-dion-(1.3) 
• 13618-27-4 1-cyclohexyl-2-methyl-pentane-1,3-dione 
• 97598-54-4 4-(4-ethyl-5-methyl-3-phenyl-4,5-dihydro-3H-[1,2,3]triazol-4-yl)-morpholine 
• 20990-23-2 2,4,6-trimethyl-3-morpholin-4-yl-cyclohex-2-enone 
• 69687-82-7 5-Ethyl-4-methylpyrrol-2-carbonsaeure-ethylester 
• 79379-51-4 2-Ethyl-3-methyl-5-phenyl-1H-pyrrole 
• 21088-38-0 6.6-Diphenyl-6-hydroxy-hexanon-⁽³⁾ 

Relevant articles and documents

Visible light induced photocatalytic conversion of enamines into amides

A series of enamines were photocatalytically cleaved to produce amide products under simple visible-light irradiation from a 45 W household light bulb. Mechanistically, the reactions appear to involve photosensitized formation of a singlet oxygen intermediate and a subsequent [2+2] cycloaddition event. Georg Thieme Verlag Stuttgart, New York.

The Chemistry of Aryllead(IV) Tricarboxylates. Reaction with Enamines

The treatment of 1-morhpholinocyclopentene (1a) with p-methoxyphenyllead triacetate (2a) in chloroform provides a simple high-yielding route to 2-(4-methoxyphenyl)cyclopentanone (3a).This arylation reaction of enamines has been investigated with a variety of substrates and a number of aryllead triacetates.The reaction has been found to be very sensitive to steric effects and is thus a useful synthetic method in a relatively small number of cases.Acetoxylation is a major competing reaction with those enamines of cyclic ketones which give a low to moderate yield of arylated product.