136546-79-7

Upstream product

• 1663-39-4 tert-Butyl acrylate 
• 131685-53-5 (S)-4-benzyl-3-propionyl-2-oxazolidinone 

Downstream Products

• 1027590-50-6 2-((R)-3-tert-Butoxycarbonyl-1-methyl-propyl)-5-phenylsulfanyl-oxazole-4,4-dicarboxylic acid dimethyl ester 
• 153180-18-8 Dimethyl <4-<(tert-butoxycarbonyl)-2(R)-methylbutyryl>amino><(phenylthio)methyl>malonate 
• 245736-60-1 C₇₅H₁₀₈N₂O₁₆Si₂ 
• 245736-69-0 C₆₉H₉₄N₂O₁₆Si 
• 245736-72-5 C₆₂H₈₈N₂O₁₆Si 
• 245736-73-6 C₆₂H₈₆N₂O₁₅Si 
• 245736-59-8 2-{6-[7-(4-benzyl-2-oxo-oxazolidine-3-carbonyl)-4-(tert-butyl-dimethyl-silanyloxy)-1-(4-methoxy-benzyloxy)-5,9-dimethyl-6-oxo-undec-10-ynyl]-2-methoxy-4-methoxycarbonylmethylene-tetrahydro-pyran-2-yl}-propionic acid benzyl ester 
• 245736-71-4 C₅₃H₇₅NO₁₃Si 

Relevant academic research and scientific papers

Asymmetric Synthesis of Calyculin A. 2. The C26-C37 γ-Amino Acid Fragments

New chiral imide enolate alkylation, aldol, and Michael addition bond constructions have been employed in the asymmetric synthesis of the C26-C37 portion of calyculin A.

Stereoselective synthesis of rapamycin fragment to build a macrocyclic toolbox

A stereoselective synthesis of a rapamycin fragment is developed and further utilized toward building a macrocyclic chemical toolbox. The amino alcohol moiety embedded in the 22-membered macrocyclic ring allowed for the addition of a variation in the chir

Enantioselective Michael Reactions. Diastereoselective Reactions of Chlorotitanium Enolates of Chiral N-Acyloxazolidinones with Representative Electrophilic Olefins

In the present study we wish to report the details of the diastereoselective reactions of titanium enolates derived from N-propionyloxazolidone 1 in inter- and intramolecular Michael reactions with ethyl vinyl ketone, methyl acrylate, and acrylonitrile (e