1365544-05-3

Upstream product

• 1365544-01-9 ClPd(CH₃C(CH₂)2)((R,Rb)-[1,1'-binaphthalene]-2,2'-diyl(2'-methoxy-[1,1'-binaphthalen]-2-yl)phosphonate) 
• 79060-88-1 sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate 
• 1365544-01-9 ClPd(CH₃C(CH₂)2)[(R,Sb)-[1,1'-binaphthalene]-2,2'-diyl(2'-methoxy-[1,1'-binaphthalen]-2-yl)phosphonite) 

Relevant academic research and scientific papers

MOP-phosphonites: A novel ligand class for asymmetric catalysis

Chiral phosphonite ligands (S,Rb)-5a, (S,Sb)-5b, (R,Rb)-6a and (R,Sb)-6b are introduced, comprising a MOP-type backbone with a binol-based binaphthyl group bound to the phosphorus. Their reaction with [Pd(η3-C4H7)Cl] 2 affords η3-methallylpalladium chloride complexes 7a/b and 8a/b which have been isolated and structurally characterised. Solid-state and solution studies indicate subtle differences in their coordination behaviour, which ultimately affects their efficacy in the asymmetric hydrosilylation of styrene. The Royal Society of Chemistry 2012.