1365544-05-3

Basic information

• Product Name: [Pd(CH₃C(CH₂)2)((R,Rb)-[1,1'-binaphthalene]-2,2'-diyl(2'-methoxy-[1,1'-binaphthalen]-2-yl)phosphonate)] tetrakis[3,5-bis(trifluor
• CAS NO: 1365544-05-3
• Molecular Weight: 1623.38
• Mol File: 1365544-05-3.mol

Chemical Properties

• CAS DataBase Reference: [Pd(CH₃C(CH₂)2)((R,Rb)-[1,1'-binaphthalene]-2,2'-diyl(2'-methoxy-[1,1'-binaphthalen]-2-yl)phosphonate)] tetrakis[3,5-bis(trifluor(CAS DataBase Reference)
• NIST Chemistry Reference: [Pd(CH₃C(CH₂)2)((R,Rb)-[1,1'-binaphthalene]-2,2'-diyl(2'-methoxy-[1,1'-binaphthalen]-2-yl)phosphonate)] tetrakis[3,5-bis(trifluor(1365544-05-3)
• EPA Substance Registry System: [Pd(CH₃C(CH₂)2)((R,Rb)-[1,1'-binaphthalene]-2,2'-diyl(2'-methoxy-[1,1'-binaphthalen]-2-yl)phosphonate)] tetrakis[3,5-bis(trifluor(1365544-05-3)

Safety Data

• Hazardous Substances Data: 1365544-05-3(Hazardous Substances Data)

Upstream product

• 1365544-01-9 ClPd(CH₃C(CH₂)2)((R,Rb)-[1,1'-binaphthalene]-2,2'-diyl(2'-methoxy-[1,1'-binaphthalen]-2-yl)phosphonate) 
• 79060-88-1 sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate 
• 1365544-01-9 ClPd(CH₃C(CH₂)2)[(R,Sb)-[1,1'-binaphthalene]-2,2'-diyl(2'-methoxy-[1,1'-binaphthalen]-2-yl)phosphonite) 

Relevant articles and documents

MOP-phosphonites: A novel ligand class for asymmetric catalysis

Chiral phosphonite ligands (S,Rb)-5a, (S,Sb)-5b, (R,Rb)-6a and (R,Sb)-6b are introduced, comprising a MOP-type backbone with a binol-based binaphthyl group bound to the phosphorus. Their reaction with [Pd(η3-C4H7)Cl] 2 affords η3-methallylpalladium chloride complexes 7a/b and 8a/b which have been isolated and structurally characterised. Solid-state and solution studies indicate subtle differences in their coordination behaviour, which ultimately affects their efficacy in the asymmetric hydrosilylation of styrene. The Royal Society of Chemistry 2012.