1365552-43-7

Basic information

• Product Name: C₂₀H₃₀OSi
• CAS NO: 1365552-43-7
• Molecular Weight: 314.543
• Mol File: 1365552-43-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₀H₃₀OSi(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₀H₃₀OSi(1365552-43-7)
• EPA Substance Registry System: C₂₀H₃₀OSi(1365552-43-7)

Safety Data

• Hazardous Substances Data: 1365552-43-7(Hazardous Substances Data)

Upstream product

• 14371-10-9 (E)-3-phenylpropenal 
• 59873-86-8 (E)-4-methyl-1-phenylpenta-1,4-dien-3-one 
• 130451-35-3 7,7-di-tert-butyl-7-silabicyclo[4.1.0]heptane 

Relevant articles and documents

Synthesis of silyloxy dienes by silylene transfer to divinyl ketones: Application to the asymmetric synthesis of substituted cyclohexanes

Silver-catalyzed silylene transfer to divinyl ketones provided 2-silyloxy-1,3-dienes with control of stereochemistry and regioselectivity. The products participated in Diels-Alder reactions with electron-deficient alkenes and imines to form six-membered-ring products diastereoselectively. Cycloaddition reactions with alkenes bearing chiral auxiliaries provided access to chiral, nonracemic cyclohexenes. The methodology, therefore, represents a synthesis of diastereomerically and enantiomerically pure products in a single flask. The highly substituted cyclohexene products could be functionalized stereoselectively to provide cyclohexanols after oxidation of the carbon-silicon bond.