136559-11-0Relevant academic research and scientific papers
Titanocene(II)-promoted cross-coupling of unsaturated compounds
Ogata, Akitoshi,Nemoto, Masami,Arai, Koutarou,Kobayashi, Kenji,Tsubouchi, Akira,Takeda, Takeshi
, p. 878 - 880 (2006)
Vinyl pivalate in the presence of the titanocene(II) reagent Cp 2Ti[P(OEt)3]2 reacts both with nonpolar C≡C triple bonds and with polar C=O double bonds, to produce conjugated dienes and allylic alcohols, respectively. Similar alkenylation also takes place when (Z)-alkenyl sulfones are treated with alkynes and carbonyl compounds. Wiley-VCH Verlag GmbH & Co. KGaA, 2006.
Synthesis of spirocyclic butenolides by ring closing metathesis
Albrecht, Uwe,Langer, Peter
, p. 4648 - 4654 (2007/10/03)
Spirocyclic butenolides were efficiently prepared by a ring closing metathesis strategy.
