136559-15-4

Upstream product

• 2550-26-7 4-Phenyl-2-butanone 
• 693-02-7 hex-1-yne 

Downstream Products

• 1220698-76-9 3-methyl-1-phenyl-4-nonyn-3-yl formate 
• 1082069-22-4 methyl 3-methyl-1-phenyl-4-nonyn-3-yl carbonate 
• 141191-66-4 cis-3-Methyl-1-phenyl-3-nonen-5-one 
• 141191-76-6 trans-3-Methyl-1-phenyl-3-nonen-5-one 
• 141191-80-2 ((E)-3-Methyl-non-2-en-4-ynyl)-benzene 
• 136559-16-5 (E)-3-Methyl-1-phenyl-non-3-en-5-one 

Relevant academic research and scientific papers

Selective synthesis of allenes and alkynes through ligand-controlled, palladium-catalyzed decarboxylative hydrogenolysis of propargylic formates

Ligand-controlled regioselective palladium-catalyzed decarboxylative hydrogenolysis of propargylic formates is described. A wide range of allenes and alkynes were obtained by using either 1,2-diphenylphosphinoethane (DPPE) or 1,6-bisdiphenylphosphinohexane (DPPH) as a catalyst ligand.

Mo-Au combo catalysis for rapid 1,3-rearrangement of propargyl alcohols into α,ss-unsaturated carbonyl compounds

The combination of Mo and cationic Au catalysts dramatically accelerated the rearrangement of diverse propargyl alcohols, which includes a short reaction time, mild conditions, and high product yields. A practical application to the highly challenging primary propargyl alcohols and the N-alkynyl amides is achieved.