136571-85-2Relevant articles and documents
CHEMISTRY OF SYSTEMS OF THE ALLYLIC TYPE. IV. KETOPROPENYLATION OF SECONDARY AMINES BY 3-HALOGENO-1-PROPENYL KETONES
Ibragimov, I. I.,Mamedov, E. I.,Ismailov, A. T.,Mekhtieva, Sh, Z.,Mamedov, N. N.,Belyaeva, V. I.
, p. 1981 - 1985 (2007/10/02)
The conditions and the stereochemistry of the reaction of secondary amines with 3-halogeno-1-propenyl ketones were determined.Substitution of the halogen atom by the secondary amino group takes place with retention of the configuration and preferred conformation of the initial chloroenone.A convenient method was developed for the production of 3-dialkylaminopropenyl ketones.