1365841-21-9

Basic information

• Product Name: (6R,7R)-8-methyl-6-{[(1R,2S,5R)-5-methyl-2-(propan-2-yl)-cyclohexyl]oxy}-5-oxa-8-azatricyclo[8.4.0.0^3,7]tetradeca-1-⁽¹⁴⁾,2,10,12-tetraen-4-one
• Synonyms: (6R,7R)-8-methyl-6-{[(1R,2S,5R)-5-methyl-2-(propan-2-yl)-cyclohexyl]oxy}-5-oxa-8-azatricyclo[8.4.0.0^3,7]tetradeca-1-⁽¹⁴⁾,2,10,12-tetraen-4-one
• CAS NO: 1365841-21-9
• Molecular Weight: 369.504
• Mol File: 1365841-21-9.mol

Chemical Properties

• CAS DataBase Reference: (6R,7R)-8-methyl-6-{[(1R,2S,5R)-5-methyl-2-(propan-2-yl)-cyclohexyl]oxy}-5-oxa-8-azatricyclo[8.4.0.0^3,7]tetradeca-1-⁽¹⁴⁾,2,10,12-tetraen-4-one(CAS DataBase Reference)
• NIST Chemistry Reference: (6R,7R)-8-methyl-6-{[(1R,2S,5R)-5-methyl-2-(propan-2-yl)-cyclohexyl]oxy}-5-oxa-8-azatricyclo[8.4.0.0^3,7]tetradeca-1-⁽¹⁴⁾,2,10,12-tetraen-4-one(1365841-21-9)
• EPA Substance Registry System: (6R,7R)-8-methyl-6-{[(1R,2S,5R)-5-methyl-2-(propan-2-yl)-cyclohexyl]oxy}-5-oxa-8-azatricyclo[8.4.0.0^3,7]tetradeca-1-⁽¹⁴⁾,2,10,12-tetraen-4-one(1365841-21-9)

Safety Data

• Hazardous Substances Data: 1365841-21-9(Hazardous Substances Data)

Relevant articles and documents

Formation of optically pure cyclic amines by intramolecular conjugate displacement

Intramolecular conjugate displacement (ICD) has been applied to the Morita-Baylis-Hillman adducts formed from (5S)-5-(l-menthyloxy)-2(5H)-furanone and aldehydes that carry a protected β- or γ-amino group. DIBAL-H reduction of the resulting ICD products releases optically pure six- or seven-membered cyclic amines having a stereogenic center α to nitrogen.