13659-80-8Relevant academic research and scientific papers
SELECTIVE FAVORSKII REARRANGEMENT IN MACROCYCLIC RINGS
Abad, Antonio,Arno, Manuel,Pedro, Jose R.,Seoane, Eliseo
, p. 1733 - 1736 (1981)
A mixture of 2,2-dibromo-12-chlorocyclododecanone (IIa) and 2,12-dibromo-2-chlorocyclododecanone (IIb) by Favorskii rearrangement gave selectively methyl 2-chloro-1-cycloundecene-1-carboxylate (IIIa).
Selective Favorskii Rearrangement of α,α,α'-Dibromochlorocycloalkanones of Medium Ring Size
Abad, Antonio,Arno, Manuel,Pedro, Jose R.,Seoane, Eliseo
, p. 2471 - 2474 (2007/10/02)
α,α,α'-Dibromochlorocycloalkanones of medium ring size have been prepared by treatment of chlorocycloalkanones with bromine and were separated by chromatography and then submitted to Favorskii reaction.The stereoisomeric reaction products have in each case been evaluated by gas chromatography and the selectivity of bromide elimination deduced.
