136603-72-0Relevant articles and documents
Foemation of 2,2-difluoro-3-hydroxymethylbenzo-1,4-oxathianes from 2-(α-trifluoromethylvinylthio)phenols
Sizov, A. Yu.,Kolomiets, A. F.,Fokin, A. V.
, p. 1381 - 1383 (1994)
It is shown that 2,2-difluoro-3-hydroxymethylbenzo-1,4-oxathianes are formed together with 3-trifluoromethylbenzo-1,4-oxathianes when ortho-(α-trifluoromethyl-β-chloroethylthio)phenols are boiled with excess aqueous alkali.The mechanism of the reaction is discussed. - Key words: ortho-(α-trifluoromethyl-β-chloroethylthio)phenols, ortho-(α-trifluoromethylvinylthio)phenols, 3-trifluoromethylbenzo-1,4-oxathianes, 2,2-difluoro-3-oxymethylbenzo-1,4-oxathianes.