136613-52-0Relevant academic research and scientific papers
Vicarious Nucleophilic Substitution of Hydrogen in Nitro-1,6-methanoannulenes
Ostrowski, S.,Moritz, R. J.,Mudryk, B.
, p. 447 - 460 (1995)
The 2- and 3-nitro-1,6-methanoannulenes and their 11,11-difluoro derivatives react with carbanions bearing leaving groups at the carbanionic center according to the Vicarious Nucleophilic Substitution of Hydrogen (VNS) scheme.The analogy between corre
Reactions of Organic Anions. Part 180. Orientation of the Carbanion Attack of Chloromethyl p-Tolyl Sulphone on 1-Cyanonaphthalene Derivatives
Makosza, Mieczyslaw,Ostrowski, Stanislaw
, p. 1093 - 1097 (2007/10/02)
The carbanion of chloromethyl p-tolyl sulphone reacts with cyanonaphthalene derivatives to give bis-annulated products and/or SNAr products and/or products of nucleophilic substitution of hydrogen depending on the structure of the substrates and on reaction conditions.The orientation of the initial carbanion attack is discussed.
