136630-36-9Relevant articles and documents
Cyclic kinetics during thermal equilibration of an axially chiral bis-spiropyran
Kundu, Pintu K.,Lerner, Avishai,Ku?anda, Kristina,Leitus, Gregory,Klajn, Rafal
, p. 11276 - 11279 (2014)
A compound combining the features of a molecular rotor and a photoswitch was synthesized and was shown to exist as three diastereomers, which interconvert via a reversible cyclic reaction scheme. Each of the three diastereomers was isolated, and by following the equilibration kinetics, activation barriers for all reactions were calculated. The results indicate that the properties of molecular switches depend heavily on their immediate chemical environment. The conclusions are important in the context of designing new switchable molecules and materials.
New AIEgens containing tetraphenylethene and silole moieties: Tunable intramolecular conjugation, aggregation-induced emission characteristics and good device performance
Yang, Jie,Sun, Ning,Huang, Jing,Li, Qianqian,Peng, Qian,Tang, Xi,Dong, Yongqiang,Ma, Dongge,Li, Zhen
, p. 2624 - 2631 (2015)
Three aggregation-induced emission luminogens (Si-pTPE, Si-tPE and Si-mTPE) were successfully obtained by the covalent incorporation of tetraphenylethene into a dibenzosilole core. Through sharing a benzene ring and changing the linkage mode between TPE a
Poly(2,7-dibenzosilole): A blue light emitting polymer
Chan, Khai Leok,McKiernan, Mary J.,Towns, Carl R.,Holmes, Andrew B.
, p. 7662 - 7663 (2005)
2,7-Disubstituted dibenzosilole monomers have been prepared by the selective trans-lithiation of 4,4′-dibromo-2,2′-diiodobiphenyl followed by silylation with dichlorodihexylsilane. Suzuki copolymerization of dibromo and bis(boronate) monomers afforded poly(9,9-dihexyl-2,7-dibenzosilole) which showed better efficiency than the corresponding polyfluorene in a single layer light emitting device. Preliminary studies demonstrated this to be a promising blue light emitting polymer. Copyright
Alternating copolymers of N-(2-ethylhexyl)-carbazole derivatives with aniline units: Synthesis and properties
Wang, Hui,Ryu, Jeong-Tak,Han, Yoon Soo,Kim, Dae-Hwan,Choi, Byeong Dae,Park, Lee Soon,Kwon, Younghwan
, p. 85/[365]-94/[374] (2006)
Alternating copolymers such as P(3,6-EHCZ-alt-Al), P(Bis-EHCZ-alt-Al) and P(2,7-EHCZ-alt-Al), based on blue-emitting carbazole and hole-transporting triarylamine units in the polymer backbone, were successfully synthesized by using palladium-catalyzed polycondensation reaction. P(Bis-EHCZ-alt-Al) exhibited blue shift both in UV-Vis absorption and PL emission, while P(2,7-EHCZ-alt-Al) showed red shift in UV-Vis absorption and blue shift in PL emission, compared to P(3,6-EHCZ-alt-Al). It was observed from the optical and electrochemical characterization that band gap energy (2.91~3.07 eV) and HOMO (-5.25~5.11 eV) levels of the copolymers could be fine-tuned by the carbazole content in the repeating unit and different reaction linkage on the carbazole ring.
Organic light-emitting device
-
, (2021/07/08)
An organic light-emitting device includes a first electrode and a second electrode facing the first electrode. An organic layer is disposed between the first electrode and the second electrode. The organic layer includes an emission layer, a first compound and a second compound.
Asymmetric pyrene derivatives comprising amine group including heteroaryl group and organic light-emitting diode including the same
-
, (2020/11/24)
The present invention relates to a pyrene derivative represented by [chemical formula A] or [chemical formula B], and an organic light emitting diode comprising the same, wherein substituents Py_1, Py_2, Ar_1, Ar_2, Z, and m are defined in the detailed de