1366454-33-2Relevant academic research and scientific papers
1,4-Induction in aldol reactions of (tertiary α′-alkoxy)methyl ketones: Synthesis of the C8-C11 stereotriad of ent-fostriecin
Cowper, Nicholas,Azzi, Soula,Dupont-Gaudet, Kristina,Burch, Jason D.
supporting information; experimental part, p. 1837 - 1839 (2012/05/04)
A diastereoselective, boron-mediated aldol process inspired by the natural product fostriecin is described. Using a tertiary α′-stereocenter as the induction element, aldol adducts are provided with high yields, good to excellent levels of diastereoselect
