13668-04-7Relevant articles and documents
Radical Alkyne peri-Annulation Reactions for the Synthesis of Functionalized Phenalenes, Benzanthrenes, and Olympicene
Tsvetkov, Nikolay P.,Gonzalez-Rodriguez, Edgar,Hughes, Audrey,dos Passos Gomes, Gabriel,White, Frankie D.,Kuriakose, Febin,Alabugin, Igor V.
supporting information, p. 3651 - 3655 (2018/03/06)
Radical cyclization reactions at a peri position were used for the synthesis of polyaromatic compounds. Depending on the choice of reaction conditions and substrate, this flexible approach led to Bu3Sn-substituted phenalene, benzanthrene, and olympicene derivatives. Subsequent reactions with electrophiles provided synthetic access to previously inaccessible functionalized polyaromatic compounds.
