136708-84-4

Basic information

• Product Name: 7-hydroxy-4-phenylsulfonyl-4-azatetracyclo<3.3.0.0^2,8.0^3,6>octane
• Synonyms: 7-hydroxy-4-phenylsulfonyl-4-azatetracyclo<3.3.0.0^2,8.0^3,6>octane
• CAS NO: 136708-84-4
• Molecular Weight: 263.317
• Mol File: 136708-84-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 7-hydroxy-4-phenylsulfonyl-4-azatetracyclo<3.3.0.0^2,8.0^3,6>octane(CAS DataBase Reference)
• NIST Chemistry Reference: 7-hydroxy-4-phenylsulfonyl-4-azatetracyclo<3.3.0.0^2,8.0^3,6>octane(136708-84-4)
• EPA Substance Registry System: 7-hydroxy-4-phenylsulfonyl-4-azatetracyclo<3.3.0.0^2,8.0^3,6>octane(136708-84-4)

Safety Data

• Hazardous Substances Data: 136708-84-4(Hazardous Substances Data)

Upstream product

• 13426-49-8 7-acetoxynorbornadiene 
• 938-10-3 phenylsulfonyl azide 
• 136708-55-9 7-acetoxy-4-phenylsulfonyl-4-azatetracyclo<3.3.0.0^2,8.0^3,6>octane 

Downstream Products

• 136708-85-5 4-phenylsulfonyl-4-azatetracyclo<3.3.0.0^2,8.0^3,6>octan-7-one 

Relevant articles and documents

Small and Medium Rings, 79. 4-Azatetracyclo2,8.03,6>octanes: New Heterocycles by Addition of Sulfonyl Azides to 7-Substituted Norbornadienes - Experimental Verification of ?* Interactions in the Norbornane Skeleton

The reaction of six 7-substituted norbornadienes with seven sulfonyl azides has been investigated.The products consist of either the novel azatetracyclic system 1 or the stereoisomeric bicycles 2 or of a mixture of them.The chemical behaviour of 1 has been studied.Mechanistically the results may be rationalized within the frame of the Mazzocchi-Houk model.The theoretical predictions of this model, concernign the ?* and ?* energies, were confirmed experimentally by using electron-transmission spectroscopy.Key Words: Cycloadditions, dipolar/ Electron-transmission spectroscopy/ Norbornane systems