13672-12-3Relevant academic research and scientific papers
Catalytic enantioselective desymmetrisation as a tool for the synthesis of hodgkinsine and hodgkinsine B
Snell, Robert H.,Durbin, Matthew J.,Woodward, Robert L.,Willis, Michael C.
, p. 16754 - 16764 (2013/03/28)
Two palladium-catalysed amination protocols are deployed in the desymmetrisation of the complex dimeric alkaloid meso-chimonanthine. The power of these transformations is showcased in an efficient formal and total synthesis of the natural products hodgkinsine and hodgkinsine B, respectively. Two palladium-catalysed amination protocols are deployed in the desymmetrisation of the complex dimeric alkaloid meso-chimonanthine. The power of these transformations is showcased in efficient formal and total synthesis of the natural products hodgkinsine and hodgkinsine B (see figure), respectively. Copyright
