136744-63-3

Basic information

• Product Name: diethyl (E)-(1-phenyl-2-butenyl)malonate
• Synonyms: diethyl (E)-(1-phenyl-2-butenyl)malonate
• CAS NO: 136744-63-3
• Molecular Weight: 290.359
• Mol File: 136744-63-3.mol

Chemical Properties

• CAS DataBase Reference: diethyl (E)-(1-phenyl-2-butenyl)malonate(CAS DataBase Reference)
• NIST Chemistry Reference: diethyl (E)-(1-phenyl-2-butenyl)malonate(136744-63-3)
• EPA Substance Registry System: diethyl (E)-(1-phenyl-2-butenyl)malonate(136744-63-3)

Safety Data

• Hazardous Substances Data: 136744-63-3(Hazardous Substances Data)

Upstream product

• 92173-10-9 (4E)-ethyl 2-ethoxycarbonyl-2,4-hexadienoate 
• 100-58-3 phenylmagnesium bromide 

Relevant articles and documents

REACTIONS OF TITANIUM DERIVATIVES OF SOME CH-ACIDS WITH CARBONYL COMPOUNDS. IV. SYNTHESIS AND SOME TRANSFORMATIONS OF DERIVATIVES OF (2-ALKENYLIDENE)MALONIC ACIDS

Ester and nitrile derivatives of (2-alkylidene)malonic acids, obtained by the condensation of (i-PrO)3Ti derivatives of CH2(CO2Et)2, CH2(CN)CO2Et, and CH2(CN)2 with α,β-unsaturated aldehydes, react with NaBH4 and RMgX to give esters and nitriles of the corresponding allylmalonic acids.These reactions are accompanied by complete retention of the geometry of the residual double bonds.The reaction of diethyl (2-alkenylidene)malonates with PhCO3H leads to the selective formation of monoepoxides and does not affect the α,β-double bond.