13675-77-9

Basic information

• Product Name: Benzenamine, N-(1,7,7-trimethylbicyclo[2.2.1]hept-2-ylidene)-
• CAS NO: 13675-77-9
• Molecular Formula: C16H21N
• Molecular Weight: 227.349
• Mol File: 13675-77-9.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzenamine, N-(1,7,7-trimethylbicyclo[2.2.1]hept-2-ylidene)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N-(1,7,7-trimethylbicyclo[2.2.1]hept-2-ylidene)-(13675-77-9)
• EPA Substance Registry System: Benzenamine, N-(1,7,7-trimethylbicyclo[2.2.1]hept-2-ylidene)-(13675-77-9)

Safety Data

• Hazardous Substances Data: 13675-77-9(Hazardous Substances Data)

Upstream product

• 736109-58-3 1,7,7-trimethyl-bicyclo[2.2.1]heptan-2-one 
• 62-53-3 aniline 
• 76-22-2 Camphor 
• 76-29-9 3-bromocamphor 
• 464-49-3 (1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one 
• 100-61-8 N-methylaniline 

Downstream Products

• 508-32-7 tricyclene 
• 5794-04-7 camphene 
• 759457-76-6 N-isobornylaniline 
• 75946-22-4 N-bornylaniline 
• 118759-88-9 N-isobornyl aniline 
• 16560-40-0 (+/-)-4-hydroxy-7,11,11-trimethyl-6-phenyl-7,8,9,10-tetrahydro-7,10-methano-2H-pyrano[3,2-c]quinoline-2,5(6H)-dione 
• 720672-58-2 rac-3-butyl-4-hydroxy-8,9,9-trimethyl-1-phenyl-5,6,7,8-tetrahydro-5,8-methanoquinolin-2(1H)-one 
• 118693-56-4 N-isobornyl-N-methylaniline 
• 17799-66-5 4-Oxo-3-phenyl-3,4-dihydro-spiro(2H-1,3-benzoxazin-2,2'-bornan) 

Relevant articles and documents

Reaction of malonates with camphoranile synthesis of 4-hydroxy-2-pyridones attached to the bornane ring system

The reaction of camphoraniles 3a,b with "magic malonates" (bis-2,4,6-trichlorophenylmalonates) 4a,b leads to 4-hydroxy-2(1H)-pyridones attached to bornane ring system 6a-c in good yields. Less satisfactory yields were obtained with the diethyl malonate 5b

Synthesis of Sterically Hindered Imines

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SYNTHESIS OF AMINES BY REDUCTION OF IMINES WITH THE MCl2/NaBH4 (M = Co, Ni) SYSTEM

A simple method for the synthesis of amines by the reduction of imines, anils and enamines, including some chiral substrates, with the MCl2/NaBH4/CH3OH reagent (M = Co, Ni) in 64-82percent yield is described.