1367626-68-3

Upstream product

• 14371-10-9 (E)-3-phenylpropenal 
• 90766-67-9 1,1-dibromo-4-phenyl-1,3-butadiene 
• 1608-03-3 (E)-but-1-en-3-yn-1-ylbenzene 
• 1378430-33-1 (E)-1-(4-phenylbut-3-en-1-yn-1-yl)-4-(trifluoromethyl)benzene 
• 1896-62-4 (E)-benzalacetone 
• 402-45-9 4-hydroxybenzotrifluoride 
• 146397-87-7 p-(trifluoromethyl)phenyl trifluoromethanesulfonate 
• 402-43-7 p-trifluoromethylphenyl bromide 

Relevant academic research and scientific papers

Regioselective hydrations of 1-aryl-3-en-1-ynes using gold and platinum catalysts: Selective production of 2-en-1-ones and 3-en-1-ones

Regiocontrolled hydrations of 1-aryl-3-en-1-ynes have been accomplished with IPrAuOTf and PtCl2/CO to yield 3-en-1-ones and 2-en-1-ones efficiently; our experimental data indicates that the sizes of catalysts play an important role. This journa

Regioselectivity switch achieved in the palladium catalyzed α-arylation of enones by employing the modified Kuwajima-Urabe conditions

A new regioselective approach to the synthesis of α-aryl enones is reported. This represents an important application of the Kuwajima-Urabe protocol toward the synthesis of this simple albeit complex functional array. Several α-aryl enones were synthesized by the palladium catalyzed arylation of triethylsilylenol ethers of enones with high regioselectivity and broad scope, utilizing sterically encumbered electron-rich phosphine ligands to drive the reaction.