1367729-74-5Relevant academic research and scientific papers
Ruthenium- and copper-catalyzed enantioselective propargylic alkylation of propargylic alcohols with β-keto phosphonates
Motoyama, Kazuki,Ikeda, Masahiro,Miyake, Yoshihiro,Nishibayashi, Yoshiaki
, p. 3426 - 3430 (2012)
The enantioselective propargylic alkylation of propargylic alcohols with β-keto phosphonates in the presence of a thiolate-bridged diruthenium complex and a copper complex as cocatalysts gives the corresponding propargylic alkylated products in excellent yields with high diastereo- and enantioselectivities (up to 97% ee).
