136773-45-0

Basic information

• Product Name: N'-(1-AMINO-2-CYANOVINYL)BENZENECARBOHYDRAZIDE
• Synonyms: N'-(1-AMINO-2-CYANOVINYL)BENZENECARBOHYDRAZIDE;N'-[(1E)-1-amino-2-cyanoeth-1-en-1-yl]benzohydrazide
• CAS NO: 136773-45-0
• Molecular Formula: C₁₀H₁₀N₄O
• Molecular Weight: 202.21
• Mol File: 136773-45-0.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: N'-(1-AMINO-2-CYANOVINYL)BENZENECARBOHYDRAZIDE(CAS DataBase Reference)
• NIST Chemistry Reference: N'-(1-AMINO-2-CYANOVINYL)BENZENECARBOHYDRAZIDE(136773-45-0)
• EPA Substance Registry System: N'-(1-AMINO-2-CYANOVINYL)BENZENECARBOHYDRAZIDE(136773-45-0)

Safety Data

• Hazardous Substances Data: 136773-45-0(Hazardous Substances Data)

Upstream product

• 53557-70-3 methyl 2-cyanoacetimidate hydrochloride 
• 613-94-5 benzoic acid hydrazide 

Downstream Products

• 136773-53-0 Benzoic acid N'-(4-amino-7-phenyl-pyrazolo[5,1-c][1,2,4]triazine-3-carbonyl)-hydrazide 
• 136773-55-2 1-Benzoyl-2,5-diamino-4-(4-methoxyphenylazo)pyrazole 
• 136773-54-1 1-Benzoyl-2,5-diamino-4-phenylazopyrazole 

Relevant articles and documents

Nitriles in Heterocyclic Synthesis: Synthesis of Pyrazolopyrimidine, Pyrazolotriazine and Pyrazolotriazine Derivatives

5-Amino-3-phenylpyrazole (1) reacted with enaminonitriles 2a-c to afford the pyrazolopyrimidines 5a,b and the 5-substituted aminopyrzole 8. 5a reacted with arenediazonium chlorides and benzaldehyde to give 6 and 7 respectively.Also, o-hydroxyacetophenone afforded the fused pyrazole derivative 9 on treatment with 1.Enaminonitrile 3 coupled with 11 and arenediazonium chlorides to give 12 and 13 respectively.Cyclization of 13a,b afforded the pyrazolotriazines 15a,b.