13678-58-5 Usage
Description
1-(Methylthio)-2-butanone has an odor reminiscent of mushroom,
with a characteristic garlic undertone. Can be synthesized from
chloro- 1 -butan-2-one.
Chemical Properties
1-(Methylthio)-2-butanone has an odor reminiscent of mushroom, with a characteristic garlic undertone
Preparation
From chloro-1-butan-2-one
Synthesis Reference(s)
Synthetic Communications, 19, p. 443, 1989 DOI: 10.1080/00397918908050685
Check Digit Verification of cas no
The CAS Registry Mumber 13678-58-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,6,7 and 8 respectively; the second part has 2 digits, 5 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 13678-58:
(7*1)+(6*3)+(5*6)+(4*7)+(3*8)+(2*5)+(1*8)=125
125 % 10 = 5
So 13678-58-5 is a valid CAS Registry Number.
InChI:InChI=1/C5H10OS/c1-3-5(6)4-7-2/h3-4H2,1-2H3
13678-58-5Relevant articles and documents
A CONVENIENT GENERAL ACCESS TO α-SULFENYLATED ACETOPHENONES AND ALKANONES
Ishibashi, Hiroyuki,Takamuro, Iwao,Mizukami, Yo-ichi,Irie, Maki,Ikeda, Masazumi
, p. 443 - 452 (2007/10/02)
Friedel-Crafts acylation of arenes with methylthio- (1) or phenylthio-acetyl chloride (2) provides ready access to α-methylthio- or α-phenylthio-substituted acetophenones.The acyl chlorides 1 and 2 reacted also with organoaluminium reagents to give α-sulfenylated alkanones.
