136786-47-5

Upstream product

• 27751-97-9 cis-4-hydroxy-6-methyl-3,4,5,6-tetrahydro-2H-pyran-2-one 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 675-10-5 4-hydroxy-6-methyl-2-pyron 

Downstream Products

• 136786-48-6 (3R,5S)-3-(tert-Butyl-diphenyl-silanyloxy)-5-hydroxy-1-(5-methyl-furan-2-yl)-hexan-1-one 
• 136786-49-7 (2R,6R,8S,10R)-10-(tert-Butyl-diphenyl-silanyloxy)-2-hydroxy-2,8-dimethyl-1,7-dioxa-spiro[5.5]undec-3-en-5-one 
• 136786-49-7 (2S,6R,8S,10R)-10-(tert-Butyl-diphenyl-silanyloxy)-2-hydroxy-2,8-dimethyl-1,7-dioxa-spiro[5.5]undec-3-en-5-one 
• 136786-50-0 (2R,6R,8S,10R)-10-(tert-Butyl-diphenyl-silanyloxy)-2-methoxy-2,8-dimethyl-1,7-dioxa-spiro[5.5]undec-3-en-5-one 
• 136786-51-1 (2R,3S,6R,8S,10R)-10-(tert-Butyl-diphenyl-silanyloxy)-2-methoxy-2,3,8-trimethyl-1,7-dioxa-spiro[5.5]undecan-5-one 

Relevant academic research and scientific papers

MODEL STUDIES TOWARDS THE SYNTHESIS OF APLYSIATOXIN. SPIRO-CONFORMATIONAL CONTROL IN THE REACTIVITY OF C2-OXIDIZED SPIROKETALS

The strategy of pre-forming a highly functionalized C2-oxidized spiroketal prior to utilizing the steric and stereoelectronic biases of the ring system to direct the introduction of further functionality is an attractive method for complex spir