136828-01-8

Basic information

• Product Name: Benzene, 1-[(1,1-dimethylbutyl)sulfonyl]-4-methyl-
• CAS NO: 136828-01-8
• Molecular Formula: C13H20O2S
• Molecular Weight: 240.367
• Mol File: 136828-01-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzene, 1-[(1,1-dimethylbutyl)sulfonyl]-4-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-[(1,1-dimethylbutyl)sulfonyl]-4-methyl-(136828-01-8)
• EPA Substance Registry System: Benzene, 1-[(1,1-dimethylbutyl)sulfonyl]-4-methyl-(136828-01-8)

Safety Data

• Hazardous Substances Data: 136828-01-8(Hazardous Substances Data)

Upstream product

• 455-16-3 p-toluenesulfonyl fluoride 
• 7569-36-0 1-(butylsulfonyl)-4-methylbenzene 
• 29182-78-3 2-Pentyl p-Tolyl Sulfone 
• 74-88-4 methyl iodide 

Relevant articles and documents

Sulfonylation of Organometallic Reagents with Arenesulfonyl Fluorides: A Simple One-Step Synthesis of Sulfones

Sulfonylation of organometallic reagents was accomplished with arenesulfonyl fluorides to provide a wide variety of alkylaryl- and diaryl sulfones.Organolithium and diorganocopper lithium reagents react smoothly with arenesulfonyl fluorides to give sulfones in high yields.Alkyl Grignard reagents often lead to mixtures of monosulfonylated and disulfonylated products.However, allylmagnesium chloride and phenylmagnesium chloride provide the corresponding sulfones in excellent yields.Organocopper reagents were also found to yield sulfones upon treatment with arenesulfonyl fluorides.By utilizing this methodology, synthetically useful alkyl, (trimethylsilyl)methyl, and allyl sulfones are easily prepared in high yields.