13685-36-4

Basic information

• Product Name: Bis-(p-chlorphenyl)-chlormethylphosphinoxid
• Synonyms: Bis-(p-chlorphenyl)-chlormethylphosphinoxid
• CAS NO: 13685-36-4
• Molecular Weight: 319.555
• Mol File: 13685-36-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Bis-(p-chlorphenyl)-chlormethylphosphinoxid(CAS DataBase Reference)
• NIST Chemistry Reference: Bis-(p-chlorphenyl)-chlormethylphosphinoxid(13685-36-4)
• EPA Substance Registry System: Bis-(p-chlorphenyl)-chlormethylphosphinoxid(13685-36-4)

Safety Data

• Hazardous Substances Data: 13685-36-4(Hazardous Substances Data)

Upstream product

• 873-77-8 (4-chlorphenyl)magnesium bromide 
• 1983-26-2 chloromethylphosphonic dichloride 
• 67260-92-8 [Bis-(4-chloro-phenyl)-phosphinoyl]-methanol 
• 15948-60-4 bis(4-chlorophenyl)phosphine oxide 

Downstream Products

• 106649-44-9 C₁₉H₁₄Cl₂NO₄P 
• 866363-66-8 thioacetic acid S-{[di-(4-chlorophenyl)phosphanyl oxide]methyl}ester 
• 1028206-14-5 [bis-(4-chloro-phenyl)-phosphanyl]-methanethiol 
• 922517-76-8 thioacetic acid S-{[bis-(4-chloro-phenyl)-phosphanyl]-methyl} ester 
• 866363-68-0 4-carboxythiobutyric acid S-{[di-(4-chlorophenyl)phosphanyl]methyl}ester 
• 866363-67-9 4-carboxythiobutyric acid S-{[di-(4-chlorophenyl)phosphanyl oxide]methyl}ester 

Relevant articles and documents

Staudinger ligation of peptides at non-glycyl residues

The Staudinger ligation provides a means to form an amide bond between a phosphinothioester and azide. This reaction holds promise for the ligation of peptides en route to the total chemical synthesis of proteins. (Diphenylphosphino)methanethiol is the mo

The effect of the phosphoryl group on the rate and mechanism of SN-substitution at the saturated carbon atoms

The reactivity of diarylphosphine oxides RR'P(O)CH2X with p-O2NC6H4ONa in DMF have been studied.The reaction rate increases with the electrodrawing properties of the substituents on R and R' in the following way: p-Me2NC6H4 2 reaction rate of diphenylphosphine oxides has been investigated.The reactivity increases as follows Cl I Br OTs.A reaction mechanism is suggested.