13685-40-0

Upstream product

• 13139-86-1 4-methoxyphenyl magnesium bromide 
• 1983-26-2 chloromethylphosphonic dichloride 
• 106649-35-8 (hydroxymethyl)di-p-anisylphosphine oxide 
• 15754-51-5 bis(4-methoxyphenyl)phosphine oxide 

Downstream Products

• 922517-75-7 thioacetic acid S-[bis-(4-methoxy-phenyl)-phosphinoylmethyl] ester 
• 922517-78-0 2-acetylamino-3-phenyl-thiopropionic acid S-{[bis-(4-methoxy-phenyl)-phosphanyl]-methyl} ester 
• 922517-74-6 2-acetylamino-thiopropionic acid S-{[bis-(4-methoxy-phenyl)-phosphanyl]-methyl} ester 
• 922517-77-9 thioacetic acid S-{[bis-(4-methoxy-phenyl)-phosphanyl]-methyl} ester 
• 1028206-13-4 di(4-methoxyphenyl)phosphinomethanethiol 
• 106649-43-8 C₂₁H₂₀NO₆P 

Relevant academic research and scientific papers

Staudinger ligation of peptides at non-glycyl residues

The Staudinger ligation provides a means to form an amide bond between a phosphinothioester and azide. This reaction holds promise for the ligation of peptides en route to the total chemical synthesis of proteins. (Diphenylphosphino)methanethiol is the mo

The effect of the phosphoryl group on the rate and mechanism of SN-substitution at the saturated carbon atoms

The reactivity of diarylphosphine oxides RR'P(O)CH2X with p-O2NC6H4ONa in DMF have been studied.The reaction rate increases with the electrodrawing properties of the substituents on R and R' in the following way: p-Me2NC6H4 2 reaction rate of diphenylphosphine oxides has been investigated.The reactivity increases as follows Cl I Br OTs.A reaction mechanism is suggested.