Cas 136853-30-0,1,5,5,8-Tetramethyl-7-oxa-tricyclo[6.3.1.0<sup>2,6</sup>]dodec-2<sup>(6)</sup>-en-4-one

136853-30-0

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Basic information

Product Name: 1,5,5,8-Tetramethyl-7-oxa-tricyclo[6.3.1.0^2,6]dodec-2⁽⁶⁾-en-4-one
Synonyms:
CAS NO:136853-30-0
Molecular Formula:
Molecular Weight: 234.338
EINECS: N/A
Product Categories: N/A

Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: 1,5,5,8-Tetramethyl-7-oxa-tricyclo[6.3.1.0^2,6]dodec-2⁽⁶⁾-en-4-one(CAS DataBase Reference)
NIST Chemistry Reference: 1,5,5,8-Tetramethyl-7-oxa-tricyclo[6.3.1.0^2,6]dodec-2⁽⁶⁾-en-4-one(136853-30-0)
EPA Substance Registry System: 1,5,5,8-Tetramethyl-7-oxa-tricyclo[6.3.1.0^2,6]dodec-2⁽⁶⁾-en-4-one(136853-30-0)

Safety Data

Hazard Codes: N/A
Statements: N/A
Safety Statements: N/A
WGK Germany:
RTECS:
HazardClass: N/A
PackingGroup: N/A
Hazardous Substances Data: 136853-30-0(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 136853-30-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,3,6,8,5 and 3 respectively; the second part has 2 digits, 3 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 136853-30:
(8*1)+(7*3)+(6*6)+(5*8)+(4*5)+(3*3)+(2*3)+(1*0)=140
140 % 10 = 0
So 136853-30-0 is a valid CAS Registry Number.

136853-30-0Upstream product

136853-26-4 7,11-epoxyisogermacrone

136853-30-0Downstream Products

136853-30-0Relevant academic research and scientific papers

Lewis acid catalysed rearrangement of 7,11-epoxyisogermacrone. Formation of a new carbon skeleton

St. Enev, Valentin,Tsankova, Elena T.

, p. 6399 - 6406 (1991)

The fluorohydrin 8 has been found to be the main product of the reaction of 7,11-epoxyisogermacrone 3 with BF3Et2O. When TMS-OTf is employed, 3 undergoes an unusual rearrangement leading to the product 10 with a new bicyclic carbon skeleton. The mechanism of the reaction is discussed.

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