136861-18-2Relevant academic research and scientific papers
STRUCTURAL EFFECTS IN THE REARRANGEMENTS OF CARBOCATIONS. DEGENERATE REARRANGEMENT OF 1-(X-PHENYL)-1,2-DIMETHYLACENAPHTHYLENONIUM IONS
Borodkin, G. I.,Bushmelev, V. A.,Nagi, Sh. M.,Rudnev, M. I.,Shakirov, M. M.,Shubin, V. G.
, p. 404 - 417 (2007/10/02)
The kinetics and mechanism of the degenerate rearrangement of 1-(X-phenyl)-1,2-dimethylacenaphthylenonium ions were studied by the dynamic NMR method.It was established that it takes place by a 1,2-aryl shift, and the transition to these ions from 9-(X-ph
