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Synthesis, Structure, and Isomerization of Diazaphosphoridine Oxides
Niecke, Edgar,Link, Manfred,Nieger, Martin
, p. 93 - 96 (2007/10/02)
The 1,2-Bis(alkyl)iminophosphane, Et3C-P=N-tBu (1), reacts with nitroso compounds, RNO (R = tBu, Ph), to form the diazaphosphoridine oxides, , 4a, b.While 4a (R = tBu) is thermally stable, 4b (R = Ph) isomerizes with formation of the benzodiazaphosphole oxide (5).The corresponding phospholimine (7) has been obtained from 1 and azobenzene.The three-membered phosphorus heterocycle 4a has been characterized by X-ray structure analysis, which reveales some remarkable features. Key Words: Diazaphosphiridine oxides
